What is chlorine in pvc?
Chlorine in PVC
PVC, short for polyvinyl chloride, is one of the most prevalent synthetic polymers known
to mankind. It is the presence of chlorine that makes PVC a unique material with a specific property set. At
its simplest, PVC is made by polymerizing vinyl chloride monomers. Vinyl chloride monomer is made of a vinyl
group (CH2=CH-) with a chlorine atom (Cl) attached. When these monomers polymerizes, it forms long chains of
PVC. It's worth noting that the chlorine content of PVC is a major constituent, with PVC typically
containing about 56% chlorine by weight.
Chlorine in PVC affects its physical properties. Chlorine
atoms are much larger atoms than the hydrogen atoms they replace in a hydrocarbon chain. Because Cl is much
bigger but is also very electronegative, this changes how the polymer chains pack up. Because of chlorine, a
more rigid and-dense structure formed. Because of this, PVC is a rigid and resilient substance, which is
also why it is frequently utilized when strength and durability are needed. Such as in the use of PVC pipes
for water supply and drainage systems, where they are resistant to high pressure and mainly exhibit low
corrosion resistance over a long time. The chlorine-containing structure also results in low gas and liquid
permeability behavior of PVC, making it useful in food packaging and industrial linings.
Chlorine
is also an important aspect of PVC’s resistance to chemicals. In PVC, the C - Cl bond is relatively strong.
This render PVC resistant to a wide variety of chemicals, including acids, bases and many organic solvents.
As a result, PVC can be used in chemical storage tanks, lab equipment and the build-out of facilities where
exposure to corrosive materials is a consideration.
The other major role of the chlorine in PVC,
however, is its fire - retardant properties. Chlorine is a halogen, and we know that halogens act as flame -
retarding agents. When PVC burns, the chlorine atoms in the polymer release hydrogen chloride gas. This gas
serves as flame - suppressant, as it lowers the amount of oxygen available to initiate the combustion, and
disrupts the chemical processes occurring inside the flame. For this reason, PVC is self - extinguishing,
which means it will burn but only as long as the intense heat is uninhibited. This trait is particularly
valuable in fields such as electrical cable insulation and building materials where fire safety is
paramount.
But the inclusion of chlorine in PVC brings up some environmental and health issues as
well. The PVC production process can also emit hazardous substances, including dioxins. Dioxins are toxic
and persistent organic pollutants, they can be generated as by-products in chlorine-based processes in the
PVC manufacturing. Moreover, HCl gas emitted in an improper combustion temperature of the incinerator can
lead to air pollution and corrosion of the incinerator equipment [16,17].
From a health standpoint,
some studies have identified risks with the leaching of certain additives from PVC products. Certain
plasticizers and stabilizers used in PVC formulations may also contain chemicals that can have endocrine -
disrupting effects. While polyvinyl chloride (PVC) is a stable polymer, additives mixed in the process can
leach from the added material over time, and worry about the release of potentially toxic additives from PVC
is compounded by its use in applications in contact with food (or water) and/or human skin.
All
I know, if you didn't read my previous article, it's the yin and yang of chlorine in PVC. These goods give
PVC excellent physical, chemical and flame-retardant characteristics that make it an exceedingly handy cloth
in countless programs. Still, the potentially health and environmentally-damaging nature of PVC's chlorine
content must be properly managed through appropriate manufacturing practices, waste strategies and product
design. Research is currently being conducted to find ways around this, and mitigate any negative polluting
aspects while still capitalizing on the positive benefits afforded by chlorine in PVC, as the push for safer
sustainable materials continues.